Groundwater quality on the territory of Kikinda municipality (Vojvodina,Serbia)     

Nenad Marić  Sanja Mrazovac Kurilić  Ivan Matić  Stanko Sorajić  Jelena Zarić 《Environmental Earth Sciences》2014,72(2):525-534

This paper provides insight into the quality of groundwater used for public water supply on the territory of Kikinda municipality (Vojvodina, Serbia) and main processes which control it. The following parameters were measured: color, turbidity, pH, KMnO₄ consumption, TDS, EC, NH₄ ⁺, Cl^?, NO₂ ^?, NO₃ ^?, Fe, Mn, total hardness, Ca²⁺, Mg²⁺, SO₄ ²⁺, HCO₃ ^?, K⁺, Na⁺, As. The correlations and ratios among parameters that define the chemical composition were determined aiming to identify main processes that control the formation of the chemical composition of the analyzed waters. Groundwater from 11 analyzed sources is Na–HCO₃ type. Intense color and elevated organic matter content of these waters originate from humic substances. The importance of organic matter decay is assumed by positive correlation between organic matter content and TDS, HCO₃ content. There is no evidence that groundwater chemistry is determined by the depth of captured aquifer interval. The main processes that control the chemistry of all analyzed water are cation exchange and feldspar weathering.  相似文献   

Environmental impact of blasting at Drenovac limestone quarry (Serbia)   总被引：1，自引：1，他引：0  

Dejan Vasović  Srđan Kostić  Marina Ravilić  Slobodan Trajković 《Environmental Earth Sciences》2014,72(10):3915-3928

In present paper, the blast-induced ground motion and its effect on the neighboring structures are analyzed at the limestone quarry "Drenovac" in central part of Serbia. Ground motion is examined by means of existing conventional predictors, with scaled distance as a main influential parameter, which gave satisfying prediction accuracy (R > 0.8), except in the case of Ambraseys–Hendron predictor. In the next step of the analysis, a feed-forward three-layer back-propagation neural network is developed, with three input units (total charge, maximum charge per delay and distance from explosive charge to monitoring point) and only one output unit (peak particle velocity). The network is tested for the cases with different number of hidden nodes. The obtained results indicate that the model with six hidden nodes gives reasonable predictive precision (R ≈ 0.9), but with much lower values of mean-squared error in comparison to conventional predictors. In order to predict the influence level to the neighboring buildings, recorded peak particle velocities and frequency values were evaluated according to United States Bureau of Mines, USSR standard, German DIN4150, Australian standard, Indian DMGS circular 7 and Chinese safety regulations for blasting. Using the best conventional predictor, the relationship between the allowable amount of explosive and distance from explosive charge is determined for every vibration standard. Furthermore, the effect of air-blast overpressure is analyzed according to domestic regulations, with construction of a blasting chart for the permissible amount of explosive as a function of distance, for the allowable value of air-blast overpressure (200 Pa). The performed analysis indicates only small number of recordings above the upper allowable limit according to DIN4150 and DMGS standard, while, for all other vibration codes the registered values of ground velocity are within the permissible limits. As for the air-blast overpressure, no damage is expected to occur.  相似文献   

Kinematics in the z = 2.81 Galaxy and the Evidence for Rotation     

Milan M. Ćirković 《Astrophysics and Space Science》2003,283(2):273-277

The existence of rotation signatures in damped Lyαabsorption systems represents a crucial test of the hypothesis that these features arise in disks of normal spiral galaxies. We apply the method for evaluating such signatures to the metal absorption lines in QSO 0528-250. In particular, the systemic redshift of the absorber is inferred from the recent detection of emission in the absorber by Möller and Warren. The kinematics of this absorber are particularly interesting because molecular hydrogen, the densest ISM component of the assumed foreground absorbing galaxy, is detected. Contrary to a recent claim, the method yields a satisfactory value for the assumed rotation velocity of the absorber.  相似文献   

Propagation of the Rossby waves on two dimensional rectangular grids     

Dr. M. B. Gavrilov  I. A. Tošić M. Sc. 《Meteorology and Atmospheric Physics》1998,68(3-4):119-125

Summary A simple two-dimensional quasi-geostrophic linearized model of the atmosphere is used to investigate the behaviour of the quasi-geostrophic modes for five horizontal rectangular grids. Numerical expressions for frequencies of Rossby waves for all grids are evaluated. It was found that the B and C grids produce only negative frequencies as well as the continuous case. The D grid has negative and zero frequencies. Finally, it was found that the A and E grids produce positive frequencies and eastward moving Rossby waves.With 2 Figures  相似文献   

A Photometric Investigation of the Eclipsing System OO Aql     

G. Djurašević  S. Erkapić 《Astrophysics and Space Science》1998,262(3):305-313

The paper is concerning with the light curve analysis of an active binary system of OO Aql. Basic orbital and physical parameters of this system were estimated by analysing photometric observations by Lafta and Grainger (1985) and Essam et al. (1992). Both groups of observations gave quite different light curves with a conspicuous asymmetry arising from unequal height of successive maxima. A slightly changed programme by Djuraevi (1992a) was applied. The programme was based on the Roche model and it included an option of overcontact configuration and active (bright or dark) spotted regions on the system's components. An inverse-problem method by Djuraevi (1992b) was used to estimate the parameters of the system and active regions. The light-curve analysis suggested a significant change in the system. For Lafta and Grainger's light curves our analysis showed the presence of a dark spotted area near the polar region of the primary component. This dark area covered about 22% of the primary's hemisphere. Essam et al.'s light curves had very complex shape. In this case the mechanism of the mass transfer and the exchange of the thermal energy between the components could produce a bright-spot (bs) area on the secondary, near the Lagrange equilibrium point L₁ around the neck region between the stars. To explain a sharp increase of the system's brightness in the B filter immediately after the secondary minimum, we had to introduce also a hot-spot (hs) area of a high temperature contrast on the secondary. With the increase of the brightness in the V-filter being of much lower intensity, this hot spot region could be taken as a local eruption. The behaviour of the B–V colour index with the orbital phase is in favour of this hypothesis also. The obtained results show that the light-curve changes are due to development and moving of active spot regions on the components.  相似文献   

Biomarker distributions as indicators for the depositional environment of lacustrine sediments in the Valjevo-Mionica basin (Serbia)     

Aleksandra Šajnović  Ksenija Stojanović  Branimir Jovančićević  Olga Cvetković 《Chemie der Erde / Geochemistry》2008,68(4):395-411

In this study, the molecular composition and biomarker distribution of lacustrine sediments from Val-1 drillhole in the central zone of the western part of the Valjevo-Mionica basin were investigated at depth interval of 0–400 m. Former investigations have shown that the core material can be separated into six depth intervals based on bulk geochemical, mineralogical and sedimentological characteristics. Concerning the quality of organic matter, presence of specific minerals, and high salinity and anoxicity, or alkalinity, three zones are of highest interest, defined at depth intervals of 15–75 m (A), 75–200 m (B) and 360–400 m (F). The first aim of the study was to identify which biomarkers characterize these specific intervals. The second aim, addressing the transitions zones of these intervals, was to extend the changes in the characteristics of the organic substance, to reflect the changes of conditions in the depositional environment as well as to define biomarker parameters which are the most sensitive sedimentological indicators.The sediments from the hypersaline anoxic and alkaline environment show high contribution of algal precursor biomass, what is in accordance with the good quality of organic substances in the sediments from these zones. High squalane content and low content of regular isoprenoid C₂₅ are typical for hypersaline anoxic environment, whereas sediments from alkaline environment have high regular isoprenoid C₂₅ content.Transition to specific sedimentation zones is characterized by change in total organic matter content, and of both free and pyrolysis-derived, and change in hydrogen index value. In the biomarker distributions, more significant changes were detected in distributions of n-alkanes and isoprenoids, compared to polycyclic alkanes. The most intensive changes in alkane distribution are reflected in changes in n-C₁₇ content compared to n-C₂₇, and phytane compared to n-C₁₈. In addition, significant sensitivity was seen in ratios between squalane and n-alkane C₂₆ (hypersaline depositional environment), or isoprenoid C₂₅ and n-alkane C₂₂ for high alkalinity environment.This study showed that Sq/n-C₂₆ ratio can be used to assess the quality of organic substance in immature lacustrine sediments.  相似文献   

Multiple discriminant analysis of the Drava River alluvial plain sediments     

Zoran Peh  Robert Šajn  Josip Halamić  Lidija Galović 《Environmental Geology》2008,55(7):1519-1535

Three discriminant function models are raised and cross-compared in order to distinguish geochemical patterns characteristic for the Drava River floodplain sediments. Based on data representing total element concentrations in samples collected from alluvium (A), terrace (T), and unconsolidated bedrock (B) at the border of a floodplain, four element clusters emerged accounting for discrimination between the referred groups of sediments. The most prominent is contaminant/carbonate cluster characteristic for alluvium. The other two are: silicate cluster typical for unconsolidated geological substrate (Neogene sedimentary rocks); and naturally dispersed heavy metal cluster separating terrace from the former two groups. Models introducing depth intervals and single profiles as grouping criteria reveal identical sediment-heavy metal matrices. The second important issue of this paper is possibility of reclassification of samples originally assigned to one of the a priori defined groups of sediments, based on established geochemical pattern. The mapped geological units can be reconsidered by the post hoc assignments to a different group if geological border between alluvium and terrace or between terrace and bedrock can not be established geologically with absolute certainty.  相似文献   

The expansion of clusters of particles under the action of atmospheric macroturbulence     

F. Mesinger  O. Milovanović 《Pure and Applied Geophysics》1963,55(1):164-174

Summary Making use of a 500 mb numerical forecast some problems of atmospheric large-scale diffusion are investigated. The expansion of various sets of clusters of particles is compared with the predictions based on the similarity theory of homogeneous turbulence. The spreading rates were in the beginning of the period of the forecast in a good agreement with the theoretical prediction, but later on they fell to the values considerable smaller than the predicted ones. The reasons of such behaviour are discussed. Furthermore the difference in zonal and meridional expansion of the clusters is demonstrated, the zonal expansion rates being more than one order of magnitude greater than the meridional ones.This work is part of the research on atmospheric macroturbulence, which has been sponsored partly by the Cambridge Research Laboratories, O.A.R. through the European Office, Aerospace Research, USAF.  相似文献   

Mercury speciation in surface and deep waters of the Mediterranean Sea     

Jože Kotnik  Milena Horvat  Emmanuel Tessier  Nives Ogrinc  Mathilde Monperrus  David Amouroux  Vesna Fajon  Darija Gibičar  Suzana Žižek  Francesca Sprovieri  Nicola Pirrone 《Marine Chemistry》2007

Mercury speciation and its distribution in surface and deep waters of the Mediterranean Sea were studied during two oceanographic cruises on board the Italian research vessel URANIA in summer 2003 and spring 2004 as part of the Med Oceaneor and MERCYMS projects. The study included deep water profiles of dissolved gaseous Hg (DGM), reactive Hg (RHg), total Hg (THg), monomethyl Hg (MeHg) and dimethyl Hg (DMeHg) in open ocean waters. Average concentrations of measured Hg species were characterized by seasonal and spatial variations. Overall average THg concentrations ranged between 0.41 and 2.65 pM (1.32 ± 0.48 pM) and were comparable to those obtained in previous studies of the Mediterranean Sea. A significant fraction of Hg was present as “reactive” Hg (average 0.33 ± 0.32 pM). Dissolved gaseous Hg (DGM), which consists mainly of Hg⁰, represents a considerable proportion of THg (average 20%, 0.23 ± 0.11 pM). The portion of DGM typically increased towards the bottom, especially in areas with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea), indicating its geotectonic origin. No dimethyl Hg was found in surface waters down to the depth of 40 m. Below this depth, its average concentration was 2.67 ± 2.9 fM. Dissolved fractions of total Hg and MeHg were measured in filtered water samples and were 0.68 ± 0.43 pM and 0.29 ± 0.17 pM for THg and MeHg respectively. The fraction of Hg as MeHg was in average 43%, which is relatively high compared to other ocean environments. The concentrations reported in this study are among the lowest found in marine environments and the quality of analytical methods are of key importance. Speciation of Hg in sea water is of crucial importance as THg concentrations alone do not give adequate data for understanding Hg sources and cycling in marine environments. For example, photoinduced transformations are important for the presence of reactive and elemental mercury in the surface layers, biologically mediated reactions are important for the production/degradation of MeHg and DGM in the photic zones of the water column, and the data for DGM in deep sea indicate the natural sources of Hg in geotectonicaly active areas of the Mediterranean Sea.  相似文献   

Factors that contributed to recent eutrophication of two Slovenian mountain lakes     

Gregor Muri  Branko Čermelj  Radojko Jaćimović  Tina Ravnikar  Andrej Šmuc  Janja Turšič  Polona Vreča 《Journal of Paleolimnology》2018,59(4):411-426

Increased eutrophication was recently observed in the 5th (5J) and 6th (6J) Triglav Lakes, two remote Slovenian mountain lakes. Sediment phosphorus (P) pools were analysed and potential external P sources affecting the lakes (atmospheric deposition, terrestrial export and nearby hut) evaluated, to assess the effects of internal and external changes on the lakes. A sequential extraction procedure was used to quantify five P fractions from the sediments: adsorbed (NH₄Cl–P), redox-sensitive (BD–P), aluminium- (NaOH–P) and calcium- (HCl–P) bound, and refractory organic (Res–P) P. Total phosphorus (TP) contents in surface sediment of 5J and 6J were 1430 and 641 µg P g^?1 dry weight sediment (dw), respectively. TP varied with depth in 5J sediments, but displayed no discernible pattern, whereas it decreased steadily downcore in 6J. Contents of all P forms were distinctly higher in 5J than 6J, but their rank order and relative abundances were similar in the two lakes. Res–P was the most abundant P fraction, followed by HCl–P. Together, the two P forms accounted for nearly 80 and 90% of TP in 5J and 6J sediments, respectively. BD–P and NaOH–P were less abundant, with each fraction accounting for 3 to 9% of TP, whereas NH₄Cl–P was least abundant. Atmospheric deposition and terrestrial export were substantial sources of P for the lakes. Delivery of the former was estimated to be at least 7.5 mg P m^?2 yr^?1 and the latter around 20 mg P m^?2 yr^?1. We concluded that P was not retained in the catchment effectively, likely because of only slightly acidic soil pH (5.9), relatively low aluminium content and high organic matter content (53%) in soils, resulting in higher vulnerability of the studied lakes to eutrophication. The mountain hut could also be a significant source of P for the lakes. Each year, it could potentially contribute ~12 kg of soluble P to the environment, but the true impact of the hut on lake trophic status remains unclear.  相似文献